| SECTION 1: Identification of the substance/mixture and of the company/undertaking |
| SERVISOL FREEZE IT 25 |
| Aerosol |
| 1.2. Relevant identified uses of the substance or mixture and uses advised against |
| 1.3. Details of the supplier of the safety data sheet |
| CRC Industries UK Ltd. |
| Wylds Road |
| Castlefield Industrial Estate |
| TA6 4DD Bridgwater Somerset |
| United Kingdom |
| Tel.: +44 1278 727200 |
| Fax.: +44 1278 425644 |
| E-mail : hse.uk@crcind.com |
| Subsidiaries | | Tel | Fax |
| CRC Industries Deutschland GmbH | Südring 9, D-76473 Iffezheim | (07229) 303.0 | (07229)30 32 66 |
| 1.4. Emergency telephone number |
| (+44)(0)1278 72 7200
(office hours) |
| SECTION 2: Hazards identification |
| 2.1. Classification of the substance or mixture |
| Classification according to 67/548/EEC or 1999/45/EC: |
| Environment: |
Not classified |
| Safety-phrase(s) : |
S2: Keep out of the reach of children. |
| Extra label elements according to Aerosol Dispenser Directive 75/324/EC: |
Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. |
| | 7 % by mass of the contents are flammable. |
| In case of contact with liquid product frostbite symptoms may occur. |
| Aerosols may explode if heated above 50°C |
| SECTION 3: Composition/information on ingredients |
| Hazardous ingredient | CAS-nr. | EC-nr | w/w % | symbol | R-phrases* | Notes |
| tetrafluoroethane | 811-97-2 | 212-377-0 | 60-100 | - | - | B |
| dimethyl ether | 115-10-6 | 204-065-8 | 5-10 | F+ | 12 | A |
| Explanation notes |
A : substance with Community workplace exposure limit |
B : substance with national established workplace exposure limit |
| Hazardous ingredient | Registration number | CAS-nr. | EC-nr | w/w % | Hazard Class and Category | Hazard statement | Notes |
| dimethyl ether | 01-2119472128-37 | 115-10-6 | 204-065-8 | 5-10 | Flam. Gas 1, Press. Gas | H220,H280 | A |
| Explanation notes |
A : substance with Community workplace exposure limit |
| (* Explanation phrases : see chapter 16) |
| SECTION 4: First aid measures |
| 4.1. Description of first aid measures |
| Contact with eyes : |
Seek immediate medical attention |
| Contact with skin : |
In case of contact with liquid, thaw frosted parts with water, remove clothing carefully and wash with soap & water |
| | Seek medical advice |
| Inhalation : |
Fresh air, keep warm and at rest. |
| Ingestion : |
In case of accident or if you feel unwell, seek medical advice (show the label where possible) |
| 4.2. Most important symptoms and effects, both acute and delayed |
| Inhalation : |
Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness |
| Ingestion : |
In case of exposure to substance or its vapours, obtain special treatment by doctor as soon as possible |
| Skin contact : |
In case of contact with liquid product frostbite symptoms may occur. |
| Eye contact : |
In case of contact with liquid product frostbite symptoms may occur. |
| 4.3. Indication of any immediate medical attention and special treatment needed |
| General Advice : |
In case of accident or if you feel unwell, seek medical advice (show the label where possible) |
| | If symptoms persist always call a doctor |
| SECTION 5: Firefighting measures |
| water, foam, carbon dioxide or dry agent |
| 5.2. Special hazards arising from the substance or mixture |
| Aerosols may explode if heated above 50°C |
| Forms hazardous decomposition products |
| CO,CO2 |
| HF may be formed |
| 5.3. Advice for firefighters |
| Keep container(s) exposed to fire cool, by spraying with water |
| In case of fire, do not breathe fumes |
| SECTION 6: Accidental release measures |
| 6.1. Personal precautions, protective equipment and emergency procedures |
| Shut off all ignition sources |
| Ensure adequate ventilation |
| Wear suitable protective clothing and gloves. |
| 6.2. Environmental precautions |
| Do not allow to enter public sewers and watercourses |
| 6.3. Methods and material for containment and cleaning up |
| Allow product to evaporate |
| 6.4. Reference to other sections |
| For further information see section 8 |
| SECTION 7: Handling and storage |
| 7.1. Precautions for safe handling |
| Keep away from heat and sources of ignition |
| Do not spray on a naked flame or incandescent material. |
| Do not pierce or burn aerosols, even after use. |
| Do not breathe aerosols or vapours. |
| Ensure adequate ventilation |
| Avoid contact with skin and eyes. |
| 7.2. Conditions for safe storage, including any incompatibilities |
| Pressurised container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. |
| Store in a well-ventilated place. |
| Keep out of reach of children. |
| SECTION 8: Exposure controls/personal protection |
| Hazardous ingredient | CAS-nr. | method | | |
| EU established exposure limits: |
| dimethyl ether | 115-10-6 | TWA | 1000 ppm |
| National established exposure limits, United Kingdom |
| dimethyl ether | 115-10-6 | TWA | 400 ppm |
| | STEL | 500 ppm |
| tetrafluoroethane | 811-97-2 | TWA | 1000 ppm |
| Control procedures : |
Ensure adequate ventilation |
| | Keep away from heat and sources of ignition |
| Personal protection : |
Take precautions to avoid contact with skin and eyes when handling the product. |
| | Ensure adequate ventilation |
| inhalation : |
In case of insufficient ventilation, wear suitable respiratory equipment. |
| hands and skin : |
Wear suitable protective gloves |
| eyes : |
Wear safety eyewear according to EN 166. |
| SECTION 9: Physical and chemical properties |
| 9.1. Information on basic physical and chemical properties |
| (for aerosols data for the product without propellant) |
| Appearance : physical state : |
Liquified gas. |
| odour : |
Characteristic odor. |
| Boiling point/range : |
Not available. |
| Evaporation rate : |
Not available. |
| Explosion limits : upper limit : |
Not available. |
| lower limit : |
Not available. |
| Vapour pressure : |
Not available. |
| Relative density : |
Not available. |
| Solubility in water : |
Insoluble in water |
| Viscosity : |
Not available. |
| SECTION 10: Stability and reactivity |
| No hazardous reactions known if used for its intended purpose |
| 10.3. Possibility of hazardous reactions |
| No hazardous reactions known if used for its intended purpose |
| 10.4. Conditions to avoid |
| Pressurized container : protect from sunlight and do not expose to temperatures exceeding 50°C. |
| Avoid overheating |
| 10.5. Incompatible materials |
| 10.6. Hazardous decomposition products |
| SECTION 11: Toxicological information |
| 11.1. Information on toxicological effects |
| Inhalation : |
Excessive inhalation of solvent vapours may give rise to nausea, headaches and dizziness |
| Ingestion : |
Ingestion is unlikely to occur |
| Skin contact : |
In case of contact with liquid product frostbite symptoms may occur. |
| Eye contact : |
In case of contact with liquid product frostbite symptoms may occur. |
| SECTION 12: Ecological information |
| 12.2. Persistence and degradability |
| 12.3. Bioaccumulative potential |
| 12.5. Results of PBT and vPvB assessment |
| 12.6. Endocrine disrupting properties |
| SECTION 13: Disposal considerations |
| 13.1. Waste treatment methods |
| Product : |
This material and its container must be disposed of in a safe way. |
| | Do not discharge into drains or the environment, dispose to an authorised waste collection point. |
| Contaminated packaging : |
Disposal should be in accordance with local, state or national legislation |
| SECTION 14: Transport information |
| 14.2. UN proper shipping name |
| Proper shipping name: |
AEROSOLS |
| 14.3. Transport hazard class(es) |
| ADR/RID - Classification code: |
5A |
| Packing group: |
Not applicable. |
| 14.5. Environmental hazards |
| ADR/RID - Environmentally hazardous: |
No |
| IMDG - Marine pollutant: |
No |
| IATA/ICAO - Environmentally hazardous: |
No |
| 14.6. Special precautions for user |
| ADR/RID - Tunnelcode: |
(E) |
| 14.7. Maritime transport in bulk according to IMO instruments |
| SECTION 15: Regulatory information |
| 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture |
| The Safety Data Sheet is compiled according to the current European requirements. |
| Dir. 2013/10/EU, 2008/47/EC amendment of the aerosol dispenser directive 75/324/EEC. |
| EU-directive 99/45/EC
|
| Regulation (EC) No 1907/2006 (REACH)
|
| 15.2. Chemical safety assessment |
| SECTION 16: Other information |
| *Explanation hazard statements: |
H220 : Extremely flammable gas. |
| | H280 : Contains gas under pressure; may explode if heated. |
This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation.
The information contained herewith is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It does not guarantee any specific properties.
Apart from any fair dealing for purposes of study, research and review of health, safety and environmental risks,no part of these documents may be reproduced by any process without written permission from CRC. |
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